#Graphene-based ink may lead to printable energy storage devices

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A key goal in graphene research is the mass production of graphene with high quality and at low cost. Energy-storage applications typically require graphene in powder form, but so far production methods have resulted in powders with a large number of structural defects and chemical impurities, as well as nonuniform layer thickness. This has made it difficult to prepare high-quality graphene inks.

In the new paper, the researchers have demonstrated a new method for preparing graphene inks that overcomes these challenges. The method involves growing nitrogen-doped graphene nanosheets over NaCl crystals using direct chemical vapor deposition, which causes molecular fragments of nitrogen and carbon to diffuse on the surface of the NaCl crystals. The researchers chose NaCl due to its natural abundance and low cost, as well as its water solubility. To remove the NaCl, the coated crystals are submerged in water, which causes the NaCl to dissolve and leave behind pure nitrogen-doped graphene cages. In the final step, treating the cages with ultrasound transforms the cages into 2-D nanosheets, each about 5-7 graphite layers thick.

The resulting nitrogen-doped graphene nanosheets have relatively few defects and an ideal size (about 5 micrometers in side length) for printing, as larger flakes can block the nozzle. To demonstrate the nanosheets’ effectiveness, the researchers printed a wide variety of 3-D structures using inks based on the graphene sheets. Among their demonstrations, the researchers used the ink as a conductive additive for an electrode material (vanadium nitride) and used the composite ink to print flexible electrodes for supercapacitors with high power density and good cyclic stability.

Read more at: https://phys.org/news/2019-06-graphene-based-ink-printable-energy-storage.html

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